也不知道新的EN 71-3 标准到底进行到什么程度了,翻遍了网络,只找到了最新的Draft的目录,大家将就看看吧(能看到新版的草案中已经给出了有机锡和铬形态分析的具体方法,包括具体要测试的有机锡的种类,等等)。十分期待有人放出全文! ,d$V-~2,
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Foreword ( hp 52Vse
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Introduction C|*U)#3:F
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1 Scope [3"k :
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2 Normative references g(& hu S
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3 Terms and definitions H
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4 Requirements &rs
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4.1 Categories of toy materials )SU
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4.1.1 Category I: Dry, brittle, dust-like or pliable material `)~]3zmG
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4.1.2 Category II: Liquid or adhesive material @6lw_E_5
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4.1.3 Category III: material scraped q]scKWYI
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4.1.4 Categories of different toy materials r1axC%
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4.2 Specific Requirements d88Dyzz
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5 Short Description bey:Qj??
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6 Reagents and Equipment qRSoF04!R
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1.6 Reagents &MZ{B/;;H
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6.2 Device Yy~xNj5OS
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7 Sampling and Sample Preparation .]H/u
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7.1 Selection of samples for analysis IL:[0q
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7.2 Preparation of standards ALn_ifNh
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7.3 Sample Preparation qRgFVX+vc
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7.3.1 Category I: Dry, brittle, smooth or powdery materials and Category II: Liquid or sticky materials GGo~39G
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7.3.2 Category III: material scraped KgbBa2@+
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4.7 migration procedures #>HY+ ;
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7.4.1 General x_I*6?
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7.4.2 Category I: Dry, brittle, smooth or powdery materials and Category II: Liquid or sticky materials j!NXNuy:
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7.4.3 Category III: material scraped 5M~+F"Hl
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8 Analysis Method V_, `?>O
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8.1 General ;]0d{
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8.2 Chromium (VI) (speciation) 2L;=wP2?{
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3.8 Organotin
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9 Calculation of results )92(C
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9.1 Standard Elements T30fp
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9.1.1 Calibration Curves
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9.1.2 Calculation of the concentration l4+ `x[^
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9.1.3 Evaluation <EgJm`V
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9.2 Chromium (III) and chromium (VI) R\&z3<-S
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9.2.1 Calibration Curves !idVF!xG
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9.2.2 Calculation of the concentration Z8ivw\|M8
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9.2.3 Evaluation 2
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3.9 Organotin $)KODI>|
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9.3.1 Calibration Curves ^J hs/HV
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9.3.2 Calculation of the migration of individual organotin compounds tl~ZuS/
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9.3.3 Calculation of the migration of organotin W(Sni[c{
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9.3.4 Evaluation SKNHLE}
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10 Test report jxm#4
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Annex A (informative) Significant technical changes between this European Standard and the previous version zx:;0Z:S6>
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Annex B (informative) Results of laboratory proficiency testing - migration of elements (May 2012) CXz9bhn<4
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Annex C (normative) Requirements for Sieve RZq_}-P,.c
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Annex D (informative) Preparation and analysis of the sample #fx"tx6
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Annex E (informative) Preparation of standards -R];tpddR5
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E.1 ICP-MS %Y#W#G
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E.1.1 stock solution (M1) #1}%=nAsi
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E.1.2 Diluted stock solution (M2) ,}>b\(Lk
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E.1.3 Work Solutions <5FGL96
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E.2 ICP-OES SD:Bw0gzrI
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E.2.1 stock solution (M1) Ne1W!0YLK
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Annex F (informative) Analysis Method <fgf L9-
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F.1 ICP-parameter _.W;hf`
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F.2 method for speciation of chromium vsB3n$2@u
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F.2.1 Scope Ff[GR$m
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F.2.2 Summary J$yJ2
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F.2.4 test equipment OlsD
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F.2.5 Method ebf/cCh
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F.2.6 reporting nX+c
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F.2.7 Example for LC-ICP-MS conditions O|&SL03Z8
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F.3 procedures for organotin O
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F.3.1 Scope n wO5<b;
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F.3.2 terms zkHyx[L
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F.3.3 Summary Jr,**,wA
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F.3.4 reagents wRe2sjM
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F.3.5 test equipment r5PZ=+F
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F.3.6 process ZEG~ek=jM
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F.3.7 Example for the gas chromatography conditions sm qUFo
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Annex G (informative) Rationale Bh()?{
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G.1 skin contact (scope) 8hZc#b;
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G.2 organotin (F.3.7.2) X^d}eWP`I
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Annex H (informative) Additional information on inspection of certain elements K9S(Xip
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Annex ZA (informative) Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC (If (created in due time)) }XRRM:B|)(
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References *r iWrG