也不知道新的EN 71-3 标准到底进行到什么程度了,翻遍了网络,只找到了最新的Draft的目录,大家将就看看吧(能看到新版的草案中已经给出了有机锡和铬形态分析的具体方法,包括具体要测试的有机锡的种类,等等)。十分期待有人放出全文! $5O&[/L
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Foreword \!Pm^FD
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Introduction T%F'4_~No
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1 Scope ]b)(=-;>
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2 Normative references ]d0Dd")n
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3 Terms and definitions 6FfDif
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4 Requirements W'[!4RQL
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4.1 Categories of toy materials fK[9<"PC0
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4.1.1 Category I: Dry, brittle, dust-like or pliable material dK=BH=S2?X
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4.1.2 Category II: Liquid or adhesive material 0KEytm]
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4.1.3 Category III: material scraped K^Xg^9
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4.1.4 Categories of different toy materials 9gjx!t>`H
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4.2 Specific Requirements !5x"d7
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5 Short Description R(ay&f%E
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6 Reagents and Equipment CfA
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1.6 Reagents X=_N7!
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6.2 Device ppfBfMX
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7 Sampling and Sample Preparation l^WFMeMD3a
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7.1 Selection of samples for analysis %)?$82=2
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7.2 Preparation of standards Y_xPr%%A
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7.3 Sample Preparation #7/_Usso
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7.3.1 Category I: Dry, brittle, smooth or powdery materials and Category II: Liquid or sticky materials 6OkN(tL&.
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7.3.2 Category III: material scraped /8VM.fr$
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4.7 migration procedures (%ra~s?
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7.4.1 General axW3#3#`
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7.4.2 Category I: Dry, brittle, smooth or powdery materials and Category II: Liquid or sticky materials "z)dz,&T
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8 Analysis Method :=WiT_M
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8.1 General r Z5vey
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8.2 Chromium (VI) (speciation) COPH)Bdq.
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3.8 Organotin
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9 Calculation of results y)iT-$bQ
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9.1 Standard Elements ^Ud1 ag!-
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9.1.1 Calibration Curves n^F:p*)Q%
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9.1.2 Calculation of the concentration IQn|0$':Z
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9.1.3 Evaluation #<_gY
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9.2 Chromium (III) and chromium (VI) Cs2hi,s
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9.2.1 Calibration Curves )Dg;W6
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9.2.2 Calculation of the concentration Qqp_(5S|>
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9.2.3 Evaluation I_/E0qSJI
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3.9 Organotin s%&/Zt
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9.3.1 Calibration Curves PM?F;mj
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9.3.2 Calculation of the migration of individual organotin compounds +%~/~1
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9.3.3 Calculation of the migration of organotin ED;rp9(
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9.3.4 Evaluation )Y &RMYy
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Annex A (informative) Significant technical changes between this European Standard and the previous version o8X? 1
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Annex B (informative) Results of laboratory proficiency testing - migration of elements (May 2012) %c@PTpAM
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Annex C (normative) Requirements for Sieve 1p8pH$j'
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Annex D (informative) Preparation and analysis of the sample %rV|{@J `
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Annex E (informative) Preparation of standards >f4[OBc
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E.1 ICP-MS | UB)q5I
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E.1.1 stock solution (M1) `7'^y
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E.1.2 Diluted stock solution (M2) FFcIOn
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E.1.3 Work Solutions ^*+M9e9Z
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E.2.1 stock solution (M1) I<,~>'cq.
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Annex F (informative) Analysis Method 6I=xjgwvf
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F.1 ICP-parameter yw%ES
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F.2 method for speciation of chromium mr_NArF
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F.2.1 Scope N>P" $
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F.2.2 Summary ]i
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F.2.3 reagents SQuW`EHBgs
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F.2.5 Method '494^1"io
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F.2.6 reporting Cqw`K P
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F.2.7 Example for LC-ICP-MS conditions JztSP?
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F.3 procedures for organotin _,]@xFCOH
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F.3.4 reagents b_JW3l
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F.3.5 test equipment ~t~5ctJ@
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F.3.6 process Ht'jm (
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Annex G (informative) Rationale Oz9k.[j(
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G.1 skin contact (scope) "VWxHRVg4M
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G.2 organotin (F.3.7.2) ]?)zH:2)
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Annex H (informative) Additional information on inspection of certain elements 1shvHmrV
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Annex ZA (informative) Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC (If (created in due time)) hcaH
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References MoFZ